In the following experimental setup of electrolysis of water, if P and Q are the gases collected in the test tubes enclosing the electrodes R and S, then select the option/options in which the matching is correct:
(i) P – Oxygen gas, R – Anode
(ii) P – Hydrogen gas, R – Cathode
(iii) Q – Hydrogen gas, S – Cathode
(iv) Q – Oxygen gas, S – Anode

- (A)(i) and (ii)
- (B)(iii) and (iv)
- (C)(i) and (iii)
- (D)(ii) and (iv)
Solution · answer (C)
- . Twice as much hydrogen as oxygen forms. Hydrogen collects at the cathode (negative electrode) and oxygen at the anode. Tube P holds the smaller volume, so it is oxygen over the anode R, and Q is hydrogen over the cathode S.
- So (i) and (iii) are correct.
Answer: (C) (i) and (iii)
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